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Q.

The decomposition of H2O2 follows first order kinetics:

H2O2(aq)H2O(l)+12O2(g)

In order to determine the rate constant of reaction , a definite volume of reaction mixture is titrated with standard KMnO4  solution, at different time. What is the value of 'X' in the following data?

Time (min)01025
Volume of  KMnO4 2520x

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a

15 ml

b

15.5 ml

c

10 ml

d

16 ml

answer is A.

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Detailed Solution

The reaction takes place as,

H2O2(aq)H2O(l)+12O2(g)

So,

80 % of  2020×0.8

=16 ml

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