Q.

The decomposition of N2O5occurs as 2N2O54NO2+O2and follows 1st order kinetics, hence 

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a

t1/2a°

b

the reaction is bimolecular

c

the reaction is unimolecular

d

None of these

answer is C.

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Detailed Solution

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Half life time (t1/2) for nth order reaction is given by, t1/2[a]1n

where n is the order of reaction and a is concentration of reactant.

As decomposition of N2O5 follows 1st order kinetic.

So, t1/2[a]11          t1/2a° 

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