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Q.

The decomposition temperature of BaCO3 (A), MgCO3 (B) and CaCO3 (C) follow the order

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a

C > A > B

b

A > C > B

c

C > B > A

d

B > C > A

answer is B.

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Detailed Solution

large xrightarrow{{;;BeC{O_3}; < ;MgC{O_3}; < ;CaC{O_3}; < ;SrC{O_3}; < ;BaC{O_3}}};:;Thermal;stability;order
As size of metal increases stability of carbonate increases
Since a larger size cation will stabilise the large size anion large left [ CO^{-2}_3 right ]
large Thermal;stability; propto ;frac{1}{{Decomposition}}
Therefore, greater the stability greater will be decomposition temperature
Decomposition temperature order:large ;BeC{O_3}; < ;mathop {MgC{O_3}}limits_B ; < ;mathop {CaC{O_3}}limits_c ; < ;SrC{O_3}; < ;mathop {BaC{O_3}}limits_A

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