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Q.

The decreasing order of acidity of following phenol derivatives is

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a

R>S>Q>P

b

S>Q>R>P

c

P>S>Q>R

d

P>Q>R>S

answer is A.

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Detailed Solution

-M and -I will increase acidity -M is effective at ortho and para positions only while -I effect will operate at all position but it is distance dependent.
+M and +I will decrease acidity but +M will be effective at ortho and para only . H-bonding in phenol derivative is also consider for the comparison of acidity.

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