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Q.

The decreasing order of basic characters of the following is:
I. Aniline                  II. o-Nitroaniline
III. m-Nitroaniline   IV. p-Nitroaniline

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a

I > II > III > IV

b

IV > III > II > I

c

I > III > IV > II

d

I > III > II > IV

answer is C.

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Detailed Solution

Plus, I group increases the electron density on the nitrogen atom. If resonance increases then only basicity decreases.

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