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Q.

The decreasing order of reactivity of m-nitrobromobenzene  (I), 2, 4, 6- trinitrobromo-benzene (II), p-nitrobromobenzene  (III), and 2,4-dinitrobromobenzene  (IV), towards OH- ions is :

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a

I>II>III>IV

b

II>IV>III>I

c

IV>II>III>I

d

II>IV>I>III

answer is B.

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Detailed Solution

More - NO2 group more will be reactivity toward HO ion towards SNAr.

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The decreasing order of reactivity of m-nitrobromobenzene  (I), 2, 4, 6- trinitrobromo-benzene (II), p-nitrobromobenzene  (III), and 2,4-dinitrobromobenzene  (IV), towards OH- ions is :