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Q.

 The degree of dissociation (α) of a weak electrolyte AxBy is related to Van't Hoff factor (i) by the expression 

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a

α=x+y-1i-1

b

α=i-1x+y+1

c

α=i-1(x+y-1)

d

α=x+y+1i-1

answer is A.

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Detailed Solution

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Ax+By   xAy++yBx-  1-α             αx        αy
Total amount of species = 1+(x+y-1)α
Vant Hoff factor = i = 1+(x+y-1)α1

α=i-1(x+y-1)

Therefore, Option A is the correct answer

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