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Q.

The degree of dissociation of PCl5 is 70% at 250°c. What is its vapour density?

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a

61 .30

b

80. 15

c

70.25

d

50.34

answer is A.

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Detailed Solution

PCl5PCl3+Cl2MNPCl5MexpPCl5=1+α=1+0.70=1.70MexpPCl5=208.51.70=122.6V.D.of PCl5=61.3

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