Q.

The density of 1.50 M solution of acetic acid (CH3COOH) is 1.05 g cm -3. The molality of the solution will be

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a

1.56 mol kg-1

b

1.46 mol kg-1

c

1.36 mol kg-1

d

1.126 mol kg-1

answer is D.

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Detailed Solution

Let there be 1 L of solution. we have n2 = 1.5 mol and V = 1 L

Mass of Solution m=Vρ=103cm31.05gcm3=1050g

Mass of acetic acid, m2=n2M2=(1.5mol)60gmol1=90.0g

Mass of Water ,m1=mm2=1050g90g=960g=0.960kg

Molarity of solution, m=n2m1=1.5mol0.960kg=1.56molkg

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