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Q.

The density of a solution containing 13% by mass of sulphuric acid is 1.09 g/mL. Calculate the molarity and normality of the solution

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a

1.445 M and 2.89N

b

0.1445 M and 0.289 N

c

14.45 M and 28.9N

d

144.5 M and 289 N

answer is A.

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Detailed Solution

Volume of 100 g of the solution =100d

=1001.09mL=1001.09×1000litre

=11.09×10 litre

Number of moles of H2SO4 in 100 g of the solution

                  =1398

Molarity =No. of moles of SoluteVolume in litre

=1398×1.09×101=1.445M

                    OR

M = M =%×d×10GMW M = 13×1.09 ×1098 M =1.445M

N = M ×basicity of acid

N = 1.445 ×2 = 2.89

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