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Q.

The depression in freezing point of water observed for the same amount of acetic acid, dichloroacetic acid and trichloro acetic acid increases in the order given above. Explain briefly.

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Detailed Solution

As we move from CH3COOH to CCl3COOH, the degree of dissociation (α ) increases. So no. of particles increases. As no.of the particles increases depression in freezing point also increases.
Order of acidic strength :
CH3COOH<CH2ClCOOH<CHCl2COOH<CCl3COOH

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