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Q.

The diamagnetic molecules are:

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a

B2, C2, N2

b

O2, N2, F2

c

C2 , N2 , F2

d

B2 ,O2, N2

answer is C.

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Detailed Solution

detailed_solution_thumbnail

C2,N2,F2 has no unpaired electron in their molecular orbital configuration representation.

B2 : σ1s2σ*1s2σ2s2σ*2s2π2py1π2pz1 : paramagnetic

C2 : σ1s2σ*1s2σ2s2σ*2s2π2py2π2pz2 : diamagnetic

N2 : σ1s2σ*1s2σ2s2σ*2s2π2py2π2pz2σ2px2 : diamagnetic

O2 : σ1s2σ*1s2σ2s2σ*2s2σ2px2π2py2π2pz2π*2py1π*2pz1 : paramagnetic

F2 : σ1s2σ*1s2σ2s2σ*2s2σ2px2π2py2π2pz2π*2py2π*2pz2 : diamagnetic

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