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Q.

The difference in the number of coulombic exchange pairs for high spin and low spin d5 ion in an octahedral complex according to crystal field theory is____

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a

2

b

4

c

0

d

None of the above

answer is D.

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Detailed Solution

High spin 3 t2g3eg2
Total exchange pairs t2g3=3 and eg2=1=4
low spin t2g5eg0 the three parallel (clock wise spin) electrons have 3 exchange pairs While the  remaining 2 have one exchange pair.

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