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Q.

The dipole moment of o, p and m-dichlorobenzene will be in the order :

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a

m > o > p

b

o > p > m

c

p > o > m

d

o > m > p

answer is D.

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Detailed Solution

The dipole moment of p – dichlorobenzene is zero because of symmetrical structure.

 o-dichlorobenzene has a higher dipole moment due to a lower bond angle than the m-isomer. Hence, the order of increasing dipole moment is :
P –dichlorobenzene  < m –dichlorobenzene  <  o –dichlorobenzene 

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The dipole moment of o, p and m-dichlorobenzene will be in the order :