Q.

The direct conversion of A to B is difficult, hence it is carried out by the following shown path ACDB

Given, ΔSAC=50eu,,ΔSCD=30 eu and,ΔSBD=20 eu, Where eu is entropy unit, then , ΔSAB is

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a

+60eu

b

-60eu

c

+100eu

d

-100eu

answer is B.

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Detailed Solution

From the given reaction sequence,

AC, ΔSAC=50euCD, ΔSCD=30euBD, ΔSBD=20eu

On adding (i) \  (ii) and subtracting (iii) from it, we get,

AB ΔSAB=ΔSAC+ΔSCD-ΔSBD

Thus, ΔSAB=(50+30-20)eu

 ΔSAB=60eu

Hence, option (B) is correct.

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The direct conversion of A to B is difficult, hence it is carried out by the following shown path A→C→D→BGiven, ΔSA→C=50eu,,ΔSC→D=30 eu and,ΔSB↔D=20 eu, Where eu is entropy unit, then , ΔSA→B is