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Q.

The dissociation constant of a substituted benzoic acid at 250C is 1.0×104. Find the pH of a 0.01M solution of its sodium salt.

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answer is 8.

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Detailed Solution

It is given to find out the pH of a 0.01M solution

 pH = 12(pKw+pKa + log c)

Sodium salt of benzoic acid is a strong base-weak acid salt.

pH = 12(pKw+pKa + log c)

pH = 12 [(-logKw)+(-logKa)+ log 0.01]

12[14 + 4 -2]

12[16] = 8.

Hence, the answer is 8.

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