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Q.

The dissociation constant of a substituted benzoic acid at  250C  is  1.0×104  Find the pH of a 0.01M solution of its  sodium salt.

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answer is 8.

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Detailed Solution

Ka=1×104    C6H5COOΘ+H2OC6H5COOH+OH 0.01(1h)     0.01h      0.01h Kb=KwKa=0.01h21hh=104 [OH]=0.01h=0.01×104=106 [H+]=108    PH=8

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