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Q.

The dissociation constant of a weak acid is  1×104 In order  to prepare a buffer solution with  a pH = 5 [Salt]/[Acid] ratio should be 

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a

1 :10

b

4 :5

c

10 :1

d

5:4

answer is C.

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Detailed Solution

pH=pKa+log[ Salt ][ Acid ] 5=4+log[ Salt ][ Acid ] pKa=logKa  Given, Ka=1×104  pKa=log1×104=4
Now from Handerson equation 

5=4+log[ Salt ][ Acid ]

log[ Salt ][ Acid ]=54=1
Taking antilog 
[Salt]/[Acid] = 10= 10: 1 

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