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Q.

The dissociation constant of a weak acid is 1×10-4. In order to prepare a buffer solution with a pH=5, the [Salt]/[Acid] ratio should be

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a

4:5

b

5:4

c

10:1

d

1:10

answer is B.

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Detailed Solution

pH=pKa+log[ Salt ][Acid] 5=-logKa+log[ Salt ][ Acid ] pKa=-logKa 5=-log1×10-4+log[ Salt ][ Acid ] 5=4+log[ Salt ][ Acid ] 5-4=log[ Salt ][ Acid ] 1=log[ Salt ][ Acid ] [ Salt ] [Acid] =10=10:1

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