Q.

The dissociation constant of a weak base is 10-4. The concentration ratio of salt to base to be maintained to keep the pH of buffer solution as 9 is

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a

10 : 1

b

1 : 10

c

1 : 2

d

2 : 1

answer is A.

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Detailed Solution

 pH + pOH = 14

9 + pOH = 14

pOH = 14 – 9 = 5

pKb=-log[Kb] = -log[10-4] = 4

pOH = pKb+log[salt][base]

5 = 4 + log[salt][base]

log[salt][base] = 5-4

= 1

[salt][base] = 1011 = 101

Hence, the correct option is option 1) 10: 1.

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