Q.

The dissociation equilibrium of a gas AB2 can be represented as

2AB2g     2AB(g)  +   B2(g)

The degree of dissociation is x and is small compared to 1. The expression relating to the degree of dissociation (x) with equilibrium constant Kp and total pressure P is

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a

2Kp/p1/2

b

2Kp/p

c

Kp/p

d

2Kp/p1/3

answer is B.

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Detailed Solution

                            2AB2g     2AB(g)  +   B2(g)

Initial moles              1                      0                 0                    

At equilibrium     21-x                 2x                 x

Total moles at equilibrium = 2 - 2x + 2x + x = (2 + x)

So,          pAB2 =  21-xp2+x,   pAB =  2xp2+x      pAB2 =xp2+x

Kp = pAB2  pAB2pAB22=2xp2+x2x2+xp 21-xp2+x 

= x3p2 + x  1-x2  =   x3p2     x  <<  1  and 2  So,  1-x    1  and 2+x    2. x = 2Kpp1/3

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