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Q.

The dissociation equilibrium pressure of NH4HS(s) is 20 cm a 270C. The total pressure at equilibrium when NH4HS is dissociated in the presence of 15 cm of NH3 is ------cm

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a

35

b

25

c

15

d

45

answer is B.

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Detailed Solution

NH4HS(s)NH3(g) + H2S(g)

given 2p = 20 cm;p = 10 cm; Kp = p2 = 100 cm2

let p' is new pressure in presence of 15 cm NH3

NH4HS(s)NH3(g) + H2S(g)

                       p' +15    p'

100 = (p'+15)(p')

p' = 5 cm

Ptotal = p'+15+p' = 5+15+5 = 25 cm

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