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Q.

The dissociation of ammonium carbamate may b represented by the equation,

NH4CO2NH2(g)2NH3(g)+CO2(g)

ΔH for the forward reaction is negative. The equilibrium will shift from right to left if there is:

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a

a decrease in pressure
 

b

an increase in temperature

c

an increase in the concentration of ammonia

d

an increase in the concentration of carbon dioxide

answer is B, C, D.

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Detailed Solution

When there is increase in temperature and increase the concentration of the product the equilibrium will shift from right to left.

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The dissociation of ammonium carbamate may b represented by the equation,NH4CO2NH2(g)⇌2NH3(g)+CO2(g)ΔH∘ for the forward reaction is negative. The equilibrium will shift from right to left if there is: