Q.

The EAN of metal atoms in Fe(CO)2NO+2 and Co2(CO)8 respectively are:

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a

34, 35

b

34, 36

c

36, 36

d

36, 35

answer is C.

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Detailed Solution

If X, Y, and Z are the amount of electrons a metal gives up, the amount of electrons that ligands give away, and the atomic number, then EAN is

EAN=Z−X+Y

For [Fe(CO)2(NO+)2],

EAN=26+2+8

EAN=36

Co2(CO)8

EAN=27+0+9

EAN=36

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