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Q.

The effect of addition of helium gas to the following reaction in equilibrium state, is:
PCl5(g)PCl3(g)+Cl2(g)

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a

Addition of helium will not affect the equilibrium.

b

Equilibrium will go backward due to suppression of dissociation of PCl5

c

Equilibrium will shift in the forward direction and more of Cl2 and PCl3 gases will be produced.

d

Helium will deactivate PCl5 and reaction will stop

answer is D.

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Detailed Solution

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Addition of inert gas to the equilibrium at constant pressure will increase the volume of equilibrium mixture. In order to restore the equilibrium pressure more gas molecules are required. PCl5(g)PCl3(g)+Cl2(g)
So in the given reaction equilibrium shift in forward direction to produce more Cl2 and PCl3 gases. (addition of inert gas to the equilibrium mixture at constant volume has no effect on the position of equilibrium)

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