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Q.

The effect of temperature on equilibrium constant is expressed  as logK2K1=ΔH2.3031T21T1;T2>T1

For endothermic reaction false statement is :

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a

1T21T1= positive 

b

K2>K1

c

logK2>logK1

d

ΔH= positive 

answer is A.

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Detailed Solution

Given That ,logK2K1=ΔH2.3031T21T1

For endothermic reaction ΔH>0,

Now for,  T2>T1

 logK2K1=ΔH2.303T2T1T1T2

 logK2K1>0logK2logK1>0

 logK2>logK1 K2>K1

1T21T1<0 since T2>T1

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