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Q.

The efficiency of a cell is 60%.  Its cell reaction is As+B2+aq.A2+aq.+B;ΔH=240kJ

The standard electrode potential of cell is

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a

0.37 V

b

1.48 V     

c

2.96 V

d

0.746 V        

answer is A.

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Detailed Solution

Thermodynamic efficiency is given by the ratio of the Gibbs function change to the Enthalpy change in the overall cell reaction.

η=GH=60100

G=-240×1000×60100as H=-240kJ/mol

G=-nFE°=144000

(Note: As n factor is 2)

E°=1440002×96500=0.746V

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