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Q.

The electrode potential of Hydrogen electrode depends upon the __________concentration, the pressure of ______________ and the temperature at which the electrode system is maintained. The electrode potential is independent of the surface area of the inert Platinum electrode.

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a

proton, monoatomic hydrogen gas

b

H+1,monoatomic hydrogen gas 

c

Pt+4,Hydrogen gas

d

H3O+1,diatomic hydrogen gas 

answer is D.

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Detailed Solution

H3O+1, diatomic Hydrogen gas H+1  ion has no independent existence. H+1ion combines with water to form H3O+1. Pure, dry diatomic Hydrogen gas has to be passed through the HCl aqueous solution to attain equilibrium. So, pressure of H2 gas decides the electrode potential. E=E02.303RT2Flog10PH2H3O+2 . The electrode potential is independent of the surface area of the electrodes.

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