Q.

The electrode potential of the following half cell at 298 K XX2+(0.001M)Y2+(0.01M)Y is________ x 10-2 V (Nearest integer).
Given Ex2+/x0=2.36V
Ey2+/y0=+0.36V 2.303RTF=0.06V

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answer is 275.

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Detailed Solution

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X(s)X2+(aq)+2e     Y2++2eY(s) Y2++X(s)Y(s)+X2+(aq)      Ecell =ε00.06nlogX2+Y2+ εcell 0=36(2.36)=2.72εcell =2.720.062log103102 =2.720.062log101=2.72+0.03 =2.75275×102 

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