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The electrolysis of 250 ml of a $N a C l$ solution was carried out for a period of 20 minutes with a current of 2.0 A. The resulting solution was titrated with 0.62 M $H N O_{3}$ solution. The volume of $H N O_{3}$ solution (in ml) required to achieve equivalence point is__________

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answer is 40.

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Detailed Solution

Eq. of $O H^{-}$ produced $= \frac{2 \times 20 \times 60}{96500} = \frac{24}{965}$

Eq. of $N a O H$ produced $= \frac{24}{965} =$ Eq. of $H N O_{3}$ needed

$\frac{24}{965} = 0.62 \times \frac{V}{1000} \Rightarrow V = 40 m l$

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