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Q.

The electron affinity of halogens are F = 322, Cl = 349, Br = 324, I = 295 kJ mol-1' The higher value for Cl as compared to that of F is due to:

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a

weaker electron-electron repulsion in Cl

b

more vacant P-subshell in Cl

c

smaller electronegativity of F

d

higher atomic radius of F

answer is A.

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Detailed Solution

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Electron affinity value of Cl is higher than that of F as Cl belongs to third period (have larger size)
while F belongs to second period (have small size). In Cl, electron-electron repulsion forces are weaker than that of F and hence, the extra electron which is to be added experience less electronic repulsions.

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The electron affinity of halogens are F = 322, Cl = 349, Br = 324, I = 295 kJ mol-1' The higher value for Cl as compared to that of F is due to: