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Q.

The electronegativity difference between N and F is greater than then between N and H yet the dipole moment of NH3(1.5D) is larger than that of NF3(0.2D) . This is because 
 

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a

in NH3 as well as NF3 , the atomic dipole and bond dipole are in opposite directions

b

in NH3  as well as in NF3 , the atomic dipole and bond dipole are in the same direction

c

in NH3  the atomic dipole and bond dipole are in the opposite directions whereas in NF3 , these are in the same direction 
 

d

in NH3  the atomic dipole and bond dipole are in the same direction whereas in NF3  these are in opposite directions 
 

answer is A.

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Detailed Solution

In NH3 the atomic dipole ( orbital dipole due to lone pair) and bond dipole are in the same direction whereas in  NF3 , these are in opposite direction so, in the former case, they are added up whereas in the latter case, net result is reduction of dipole moment. It has been shown in the following figure: 
   Question Image

 

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