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Q.

The electronic configuration of gadolinium (Atomic number 64) is

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a

[Xe]4f75d16s2

b

[Xe]4f85d66s2

c

[Xe]4f35d56s2

d

[Xe]4f75d26s1

answer is C.

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Detailed Solution

The electronic configuration of La (Z = 57) is [Xe]5d16s2.Therefore, further addition of electrons occurs in the lower energy4f-orbital till it is exactly half-filled at Eu(Z = 63). Thus, the electronic configuration of Eu is [Xe]4f76s2. Thereafter addition of next electron does not occur in the more stable exactly half-filled 4f7 subshell but occurs in the little higher energy 5d-orbital.
Thus, the electronic configuration of Gd(Z = 64) is  [Xe4f75d16s2.  

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