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The electronic spectrum of ${[Ti {(H_{2} O)}_{6}]}^{3 +}$ shows a single broad peak with a maximum at $20, 300 {cm}^{- 1}$ . The crystal field stabilization energy (CFSE) of the complex ion, in ${kJ mol}^{- 1}$ , is : $(1 {kJ mol}^{- 1} = 83.7 {cm}^{- 1})$

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83.7

145.5

242.5

answer is D.

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Detailed Solution

${[T i {(H_{2} O)}_{6}]}^{3 +}, T i^{3 +}, 3 d^{1}$ in octahedral field of ligand

$C F S E = - 0.4 Δ_{0}$

$C F S E = \frac{- 0.4 \times 20300}{83.7}$

$= 97 kJ mol$

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