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Q.

The electronic spectrum of  [Ti(H2O)6]3+  shows a single broad peak with a maximum at  20,300cm1.The crystal field stabilization energy (CFSE) of the complex ion, in  kJmol1, is:  (1kJmol1=83.7cm1)  

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a

83.7

b

145.5

c

242.5

d

97

answer is D.

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Detailed Solution

[Ti(H2O)6]3+,Ti3+,3d1 in octahedral field of ligand

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CFSE=0.4Δ0     CFSE=0.4×2030083.7=97kJmol

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