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Q.

The elemental composition of a compound is 54.2% C, 9.2% H and 36.6% O. If the molar mass of the compound is 132 g mol–1, the molecular formula of the compound is : 
[Given : The relative atomic mass of C : H : O = 12 : 1 : 16]

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a

C6H12O3  

b

C4H9O3

c

 C6H12O6 

d

 C4H8O2 

answer is C.

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Detailed Solution

C             :    H          :       O54.212      :    9.2           :    36.6164.516      :    9.2      :    2.2874.5162.287    :    9.22.287    :    2.2872.2871.97       :    4.02        :    1
C2H4Empirical formula 
E.F. mass = 24 + 4 + 16 = 44 and molar mass = 132 
Hence molecular formula = (C2H4O)3 
                                              = C6H12O3 
Correct Option (3)

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The elemental composition of a compound is 54.2% C, 9.2% H and 36.6% O. If the molar mass of the compound is 132 g mol–1, the molecular formula of the compound is : [Given : The relative atomic mass of C : H : O = 12 : 1 : 16]