Q.

The emf of the cell Zn|Zn+2(0.01m)||Fe+2(0.001M)|Fe at 298 K is 0.2905 volt. Then the value of equilibrium constant for the cell reaction is.

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a

100.32/0.0295

b

100.32/0.0294

c

100.26/0.0295

d

100.32/0.0591

answer is B.

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Detailed Solution

Zn+Fe+2 Zn+2+Fe(n=2)
E=E°0.0591nlog(1)
0.02905=E°0.0591nlog0.010.001
E°=0.02905+0.02905=0.32V
But at equilibrium,E=0
E°=0.05912logKeq
0.32=0.02945logKeq

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