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Q.

The empirical formula of a non-electrolyte is CH2O. A solution containing 6g of the compound exerts the same osmotic pressure as that of 0.05M glucose solution at the same temperature. The molecular formula of the compound is 

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a

C4H8O4

b

C3H6O3

c

C5H10O5

d

C2H4O2

answer is D.

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Detailed Solution

For isotonic solution : w1m1V1=w2m2V2

w1=mass of glucose=0.05×180g=9g

m1=molecular mass of glucose=180g

Assuming V1=V2=1L

w2=mass of compound =6g

m2= molecular mass of compound = ?

9180=6xx=120g Molecular mass  Empirical mass =nn=12030=4

 Molecular formula =C4H8O4

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