Q.

The energies of activation for forward and reverse reaction for A2+B22AB are 180 kJ mol1 and 200 kJ mol1 respectively. The presence of catalyst lowers the activation energy of both (forward and reverse) reactions by 100 kJ mol1. The enthalpy change of the reaction (A2+B22AB) in the presence of catalyst will be (in kJ mol1): 

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a

120

b

280

c

-20

d

300

answer is D.

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Detailed Solution

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So, ΔHreaction=EfEb

                       =80100 =20 kJ mol1

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The energies of activation for forward and reverse reaction for A2+B2⇌2AB are 180 kJ mol−1 and 200 kJ mol−1 respectively. The presence of catalyst lowers the activation energy of both (forward and reverse) reactions by 100 kJ mol−1. The enthalpy change of the reaction (A2+B2→2AB) in the presence of catalyst will be (in kJ mol−1):