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Q.

The energy of a vibrating molecule is quantized much like the energy of an electron in the hydrogen atom. The energy levels of a vibrating molecule are given by the equation, En=(n+12)hν , where n is a quantum number with possible values of 1 , 2 ...... and ν  is the frequency of vibration. The vibration frequency of HCl is approximately 9×1011s1 . If the minimum energy is required to excite a vibration in HCl is  ΔE , the wavelength of light required to excite this vibration is______  μm.
[Given h=6.6×1034Js&c=3×108ms1 , Molar mass of HCl = 36.5 g/mol]
 

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answer is 333.33.

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Detailed Solution

ΔEmin=E2E1=hν

hcλ=hνλ=3×1089×1011=39×103m=30009μm

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