Q.

The energy required to break one mole ClCl  bond in Cl2  is 242KJ/mol. The longest wavelength of light capable of breaking a single ClCl   bond is x nm 
 (C=3×108m/s,NA=6.023×1023mol1,  h=6.6×1034J ) The value of x is (nearest integer)
 

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answer is 493.

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Detailed Solution

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Energy required to break one 

ClCl  bond  =242×103J6.02×103

E=hcλ   or  λ=LCE

λ=6.6×103×3×108×6.023×1023242×103=493×109m  =493mm

:x=493Mm

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