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Q.

The energy required to break one mole of Cl – Cl  bonds in C12 is 242 kJ  mol1. The longest wavelength of light capable of breaking a single Cl – Cl bond is (c=3×108ms1  and  NA=6.02×1023mol1)

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a

640 nm

b

494 nm

c

700 nm

d

594 nm

answer is D.

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Detailed Solution

E=242×1036.023×1023=hcλ

=6.626×3×6.023×103242×103

=0.4947×106m

λ=494.7mm.

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The energy required to break one mole of Cl – Cl  bonds in C12 is 242 kJ  mol−1. The longest wavelength of light capable of breaking a single Cl – Cl bond is (c=3×108ms−1  and  NA=6.02×1023mol−1)