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Q.

The enthalpies of combustion of carbon and carbon monoxide are 390 KJ mol-1 and 278 KJ mol-1 respectively. The enthalpy of formation of carbon monoxide is

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a

668 KJ mol-1 

b

112 KJ mol-1 

c

-668 KJ mol-1 

d

-112 KJ mol-1 

answer is C.

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Detailed Solution

Given data: The enthalpies of combustion of carbon and carbon monoxide are 390 KJ mol-1 and 278 KJ mol-1 respectively.

Formula/Concept used: Hess’s law

Detailed solution: The reactions are given below:

C+O2CO2; ΔH = -390 KJ..........(i) CO+12O2CO2; ΔH = -278 KJ..........(ii)

The required reaction is:

C+12O2CO 

The required reaction be formed by subtracting equation (ii) from (i).

The enthalpy of the reaction is:

ΔH = -390 - (-278) ΔH = -112 KJ

Therefore, the correct option is C.

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