Q.

The enthalpies of formation of gaseous N2O and NO at 298 K are 82.0 and 90.0KJ mol-1 respectively. The enthalpy change of the reaction N2O(g)+12O2(g)2NO(g) is 

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a

+89 kJ

b

+98 kJ

c

-74 kJ

d

-47 kJ

answer is B.

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Detailed Solution

N2+12O2N2O, H1=82.0 kJ/mol...(i) 12N2+12O2NO, H2=90.0 kJ/mol...(ii)

Reverse equation (i), multiply equation (ii) by 2. Then subtract (ii) from (i).

12N2+12O2NO, H2=90.0 kJ/mol...(ii)×2 N2ON2+12O2, H1=-82.0 kJ/mol...(i) N2+O22NO, H2=180.0 kJ/mol...(ii) N2O+12O22NO, H=98 kJ/mol

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