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Q.

The enthalpies of neutralization of HCIO4 and CI3C-COOH are 
- 13.5 kcal/g - equivalent and
- 13.5 kcal/g - equivalent respectively
when 40 g of solid NaOH is added to a mix of 1 g mol.
HClO4 and 1 g mol CI3C-COOH, sodium perchlorate and sodium trichloroacetate are formed in molar ratio of 3:1.
Then,

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a

H for the reaction of NaOH with the mix. is 6.45 kcal.

b

H for the reaction of NaOH with the mix. is 13.8 kcal.

c

After reaction the total no. of moles of acid remained are 0.5 (HClO4 and CI3C-COOH)

d

After reaction the total weight of acid remained is 147.75 g. (HClO4 + Cl3Cl-COOH) and H for the reaction of NaOH with mix. is -13.8 kcal.

answer is D.

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Detailed Solution

HClO4+NaOHNaClO4+H2OCl3CCOOH+NaOHCl3CCOONa+H2O

Let x mol ofNaOH are used in first reaction and (1 - x) mol of NaOH are used in second reaction.

 Given x1x=3x=34ΔH=13.5×34+(14.7)×14=40.5+14.74=13.8kcal

 Weak acids =34(1+35.5+64)+334(35.5×3+24+32+1) = 147.75 g

 

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