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Q.

The enthalpy change for a given reaction at 298 K is xJ mol1 (x being positive). If the  reaction occurs spontaneously at 298 K, the entropy change at that temperature :

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a

cannot be positive

b

cannot be negative

c

can be negative but numerically larger than  x/298

d

can be negative but numerically smaller than x/298

answer is B.

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Detailed Solution

The entropy change at this temperature,

ΔS<x298
 

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