Q.

The enthalpy change on freezing of 1.0 mole of water at 100C to ice at 100C is

[Given ΔfusH=6.03kj/moleat00CCpH2O(l)=75.3J/mole.k CpH2O(s)=36.8J/mole.k

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a

-715.1j/mole

b

-368j/mole

c

-7.151 Kj/mole

d

+7.151Kj/mole

answer is A.

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Detailed Solution

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1moleofH2Oat100CΔH11moleofH2Oat00CΔH21moleoficeat  00CΔH31moleoficeat100CΔHTotal=ΔH1+ΔH2+ΔH3

ΔH1=CpΔT=75.3010=753j/mole=0.753kj/mole

ΔH2=6.03kj/mole

ΔH3=CpΔT=36.8100=368j/mole=0.368kj/mole

ΔHTotal=0.7536.030.368=7.151kj/mole

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