Q.

The enthalpy change when x g of phenol dissolves in y g of CHCl3 is given below at a certain temperature.  

XYΔH (kcal)
0.470120-0.02
1.410140-0.03

What is magnitude of enthalpy of dilution per mole of phenol, when the second solution is diluted to the concentration of the first by addition of CHCl3. (give value to nearest integer in Kcal/mol )

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answer is 2.

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Detailed Solution

phOH(solution II)  phOH(solution I)

ΔH=(0.020.47×94)(0.031.410×94)=2kcal/mol

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