Q.

The enthalpy of formation of H2O(1) is - 290 kJ / mol and enthalpy of neutralization of strong acid with strong alkali is - 56 kJ / equiv. what is the enthalpy of formation of OH-  (aq)? Given Δform HH+,aq=0

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a

- 346 kJ / mol

b

- 234 kJ / mol

c

- 178 kJ / mol

d

- 334 kJ / mol

answer is B.

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Detailed Solution

H2(g)+12O2(g)H2O(l); ΔH1=290kJ

H++OHH2O; ΔH2=56kJ12H2H+(aq); ΔH=0 12H2(g)+12O2(g)OH(aq)ΔrHΔrH=290+56=234kJ/mol

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