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Q.

The enthalpy of formation of N2Og and NO(g) are 82 and 90 KJ/mol respectively. The enthalpy of the reaction 2N2Og+O2g 4NOg  is

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a

80 KJ

b

-16.0 KJ

c

88.0 KJ

d

196.0 KJ

answer is D.

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Detailed Solution

The reaction of formation of N2Ogis given below:

N2+12O2N2O...........(1) 

The enthalpy of this reaction is 82 KJ/mol.

The reaction of formation of NO(g) is given below:

12N2+12O2NO...........(2) 

The enthalpy of this reaction is 90 KJ/mol.

Multiplying the equation (1) by 2 and equation (2) by 4, we get:

2N2+O22N2O...........(3)

The enthalpy of this reaction is 164 KJ/mol.

2N2+2O24NO...........(4) 

The enthalpy of this reaction is 360 KJ/mol.

 Subtracting equation (3) from (4), we get the required reaction in the question. So, the enthalpy of the reaction can be calculated as:

ΔH=360-164=196 KJ 

Therefore, the correct option is D.

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